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The enthalpy energies are calculated by using exothermic peaks of differential (thermal analysis (DTA) en Cobalt-Boron liquid quenched amorphous alloys. The endothermic peaks are not distinctly recorded. The diffusional recovery processes in Co-B LQA alloys occur at about 693K and temperatures less than 800K; which suggests that the polymorphic transformation of cobalt is responsible for diverse diffusion recovery processes such as intestinal and vacancy formations, Cottrell-Lomer locks, point defects due to free covalent bonds (dangling bonds), edge/edge and screw/screw annihilations through forced climb due to thermal stresses and indeed due to non-operative slip systems of cobalt (both basal and pyramidal slips). Structural changes in Co-B LQA alloys occur at above 800K mainly due to operative slip systems in Cobalt (both basal and pyramidal) which cross each other (cross-slip) due to thermal stresses and annealing. The cross-slip in o p.h. metals (cobalt) particularly allow temperatures is indeed difficult.read more
A HUSSIAN ,S M RAZA ,S M M R NAQVI ,S D H RIZVI ,S RIZVI ,F REHMAN ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 1
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The dissociation constants (pKa4) and thermodynamic parameters Gibb's free energies (DG) have been determined by a potentiometric pH titration of 8-hydroxyquinoline (oxine) in water at 25 to 50°C and for 24-methylquinoline in water and in aqueous binary mixtures of dioxane, ethanol (EIOH) and methanol (MeOH)at 25°C ± 0.l°C. The first and second dissociates constants of oxine have been analyzed and discussed with (DG) thermodynamic parameters. The pK values and thermodynamic parameters of 2. methylquinoline have also been computed and discussed in term of solute-solvent interactions. The curves found in both the compounds are a part of a parabola and these follow quadratic equations. The results are correlated with dielectric contants of medium and discussed in term of solvent characteristics, solvent basicity and stabilization of conjugate acid for base by hydrogen bonding interaction in hypo-organic solvent media.read more
A W K KHANZADA ,H A B INDHAR ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 3
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The dyed cotton fabrics after dyeing are usually treated with different auxiliaries to impart desirable properties according to their commercial uses in industries. An attempt has been made to improve the wash fastness and colour properties of eleven non-benzidine direct dyes based on 4,4'-diaminostilbene-2,2'-disulphonic acid. The effectiveness of three fixing agents used was determined by comparing the properties of treated and untreated dyed substrate. All the three fixing agents showed beneficial effects on these properties as assessed by ISO CO 5 wash fastness and on the colour properties like tristimulus values, CIE L*a*b* co-ordinates, chromaticity co-ordinates and Munsell values. Use of these fixing agents improved the wash fastness of these dyes on cotton as well as the brightness and strength of the colour in a similar pattern.read more
C M ASHRAF ,S WAHEED ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 10
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Nowadays, environmental monitoring has great importance and mercury is well known for its toxicity. Mercury (which is at trace level) is analyzed by cold vapor atomic absorption spectroscopy with amendments that are appropriate to the present laboratory need. The results are consistent with previous analysis, through other methods. Two areas namely Ibrahim Hyderi and Fisheries were found to have mercury levels around 0.193 µg/L and 0.110µg/L, respectively. Whereas other areas have mercury levels similar to other places reported earlier.read more
J SHAZLI ,S RAJABALI ,S MOHIUDDIN ,I I NAQVI ,I ZEHRA ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 18
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The kinetics and mechanism of the reduction of ferric 1,10 arthophenanthroline by Uranium (IV) ethylenediammine tetra acetate was investigated in aqueous hydrochloric acid at 25°C, ionic strength 0.01 mol dm-3 and pH 3.5. Rate law for the formation of Fe (II) opt was established through spectrophotomeiric measuresed at constant and varying pH by isolation method. At pH of 3.5 and temperature of 25°C, the order of reaction was found to be second having the value of 221 M-1 mind and rate law is suggested to be d/dt [Fe(opt)3 ]+2 = K1 [U(IV) EDTA H+ } [Fe(opt)3 ]+3. Differed thermodynamic functions for the reaction were Ea= 3.37 KJ mol-1, DG = -42 KJ mol-1, DH-2 KJ mol-1and DS =148 J K4 mol-1. At different pH values the rate law was observed as rate = Kk1[H+] [ U(IV) EDTA ] [Fe(opt)3 ]+2, where K is equilibrium constant for the reaction [U(IV) EDTA] + [H+] - [ U(IV) EDTA H+ ] and k1 is the specific rate constant for the reaction [U(IV)EDTA H]+ + [Fe(opt)3]3+® [U(V)EDTA] + [Fe(opt)3]2+.read more
M QADRI ,M A FARRUKH ,I I NAQVI ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 21
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Effects of various solvents on the infrared spectra of propanoic acid were studied. Fundamental vibrations v(0-H), &(0-H) and v (C-O) were investigated with respect to solvent change. The v (C=O) vibration was also studied in a binary mixture of carbon tetrachloride and acetonitrile. Results were interpreted in terms of solute-solvent interactions.read more
N RAUF ,M IKRAM ,M A RAUF ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 25
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Organotin compounds are very useful in all walks of life. These compounds have an advantage over other metallic compounds, since the inorganic tin species formed upon degradation are non toxic, no environmental pollution. Organotin compounds were synthesized and analysed. The identity of products were confirmed by classic and modem techniques.read more
M H Z CHAUDHRY ,R G REES ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 27
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Model chiral 3-acetyl4,5-dihydro-1,2,4-triazinones 1a-e were reacted, utilizing the template effect, with 1,3-diaminopropane in the presence of nickel acetate. The resulting chiral open chain tetranza-type nickel complexes 2a-c were characterized by elemental analysis and NMR spectral data. Their CD spectra in organic solvents revealed the same features for the masked aliphatic and aromatic amino acid residues of the same L-configuration. The stereochemistry at C-5 is correlated with the signs of the observed CE bands.read more
R M EL ABADELAH ,M H Z CHAUDHRY ,W VOELTER ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 31
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A new, simple and rapid Disc electrophoresis method has been developed in our laboratory for determination of different oxidation states of Iron and copper singly as well as in mixture form through the specially prepared glass tubes of polacrylamide gel using glycine buffer at pH 4 and 3.5. For quantitative analysis the intensity of electrophoratically separated colored bands of respective metal ions in the tubes were measured using Thin layer chromatographic scanner CS-910. Ne developed plates were scanned separately in UV, Vis and fluorescence regions on pre-determined wavelengths simultaneously integration and profile mode. It has been observed that, very sharp Disc bands with particular colour of both cations with different oxidation state were obtained with approximately ten micron thickness. The detection limits has been achieved in the range of mg/µl level.read more
M A JAKHRANI ,T G KAZI ,M F KHAH ,M H S WATTOO ,G H KAZI ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 35
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The quality of drinking water is regulated in most countries under recommendation and legal requirements. For developing countries regulations are framed by World Healh. Organization (WHO) since 1984 and onwards. Normally ground water and surface water (River, lacks, springs) are used for bottler's choice of water.In the present paper we have evaluated the pure water supplied by many factories in bottles with different brand names. Such mineral water was analyzed for different physical and chemical parameters. The quality of bottled water is compared with U.S. Federal Drug Administration (FDA) guidelines for bottled water and World Health Organization standards for drinking water.read more
T G KAZI ,M H S WATTOO ,F ANWAR ,M A JAKHRANI ,
- 18 Apr 2011
- Volume Detail: VOLUME 24, NO1, MAR 2002
- Pages: 39
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